MATERIAL SAFETY DATA SHEET
| Sheet No. 151 | Revision Date: 31 January 2012 |
|
|
|
MATERIAL SAFETY DATA SHEET |
||
| HMIS: Health- 2 Flammability- 2 Reactivity- 0 Pers. Protection- B |
NFPA: Health- 2 Flammability- 2 Reactivity- 0 Special Hazard- N |
WHMIS:
D 2 B | ||
Section 1: Product and Company Identification |
Product: Para Deodorizing Blocks, all
|
Synonyms: |
| NILODOR, INC. | |
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA |
|
Non-Emergency: |
24 hr Emergency Spill Information: |
US 800-443-4321
|
Chem-Tel, Inc. |
International 010-330-874-1017
|
US, Canada: 800-255-3924. International: 1-813-248-0584 |
Section 2. Hazards Identification
|
| EMERGENCY OVERVIEW | |
| Appearance/Odor: | Cake-like solid. See section 9 |
| NOT Classified as hazardous by the criteria of NOHSC. | |
| WARNING | |
| Flammability : | Not classified as flammable |
| Health Hazards Listed : See below | |
| Ecological Hazards Listed : Moderately toxic to aquatic organisms | |
| Potential Health Effects: See section 11 for more information. | |
| Likely Routes of Exposure: Ingestion, Inhalation | |
| Eye: | Direct exposure can irritate |
| Skin: | Prolonged or repeated exposure can irritate |
| Ingestion: | Harmful if swallowed |
| Inhalation: | Can irritate respiratory tract |
| Medical Conditions Aggravated By Exposure: | |
| Respiratory problems | |
| Target Organs: | Liver, kidney in high dosages |
| This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. | |
| This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). | |
| Potential Environmental Effects: (See section 12 for more information.) | |
| Biodegradable | |
Section 3. Composition/Information on Ingredients
|
| Component | CAS# | % by Weight | WHMIS Controlled |
| 1,4-Dichlorobenzene | 106-46-7 | 60-100 | Y |
| Trade Secret Fragrance Mixture | None | 0 - 2.0 | N |
| Trade secret dye mixture | None | 0 - 2.0 | N |
| Only known ingredients |
Section 4. First Aid Measures |
| Eye Contact: | Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician. |
| Skin Contact: | Wash with soap and water. |
| Inhalation: | Remove to fresh air. |
| Ingestion: | If conscious, give water or milk to drink. |
| Note to Physicians: | Emesis not recommended. If removal from stomach is indicated, gastric lavage may be used. |
Section 5. Fire Fighting Measures |
| Suitable Extinguishing Media: | Carbon dioxide, foam, dry chemical. |
| Unsuitable Extinguishing Media: | None known. |
| Products of Combustion: | Chlorine, hydrogen chloride, phosgene, oxides of carbon and chlorine. |
| Protection of Firefighters: | If large quantities of product involved, use self-contained breathing apparatus. |
Section 6. Accidental Release Measures
|
| Personal Precautions: | Keep away from skin and eyes. Rubber or other protective gloves recommended for handling product. |
| Environmental Precautions: | Keep out of surface waters and sanitary sewers. |
| Methods for Containment: | Not normally needed; product is solid at ambient temperatures. |
| Methods for Clean-Up: | If any inner cellophane wrappings are torn, wear protective gloves. Gather or shovel up scattered units. |
| Other Information: |
Section 7. Handling and Storage
|
| HANDLING |
| Do not open inner package until ready to install. |
| STORAGE |
| Keep out of the reach of children. Store in original container at ambient temperature, not more than 50°C/120°F. |
Section 8. Exposure Controls/Personal Protection |
| EXPOSURE GUIDELINES | ||
| COMPONENT: | TWA: | LD-50 |
| 1,4-Dichlorobenzene | TLV 10 ppm | 3790 mg/kg |
| Trade Secret Fragrance Mixture | None established | Not determined |
| Trade secret dye mixture | None established | Not determined |
| Only known ingredients | ||
| Engineering Controls: Not normally necessary when handling individual blocks | ||
| Eye/Face Protection: Not normally necessary when handling individual blocks | ||
| Skin Protection: Rubber or other protective gloves recommended if handling block outside inner package | ||
| Respiratory Protection: Not normally necessary. | ||
| General Hygiene Considerations: Keep away from food and beverages | ||
Section 9. Physical and Chemical Properties
|
| Color: Pink - light red (Cherry) or white - pale yellow (Cherry or Lemon) | Odor: Cherry or lemon + characteristic \"\"mothball\"\" |
| Physical State: Cake-like solid. May be enclosed in white plastic cage. | Odor Treshhold: |
| pH: Not applicable | Freezing Point: Not applicable |
| Evaporation Rate: Not determined | Boiling Point: 174°C/345°F |
| Flash Point: 150°C/302°F | Flammability(solid,gas): Not considered a flammable solid |
| Upper Flammability Limit: Not determined | Lower Flammabilty Limit: 2.5% at 142°C/287°F |
| Vapor Pressure: 0.59 Torr at 20°C/68°F | Specific Gravity: 1.25 |
| Vapor Density: 5.1 (air = 1) | Auto-ignition Temperature: Not determined |
| Volatile Organic Compound (VOC),%weight: | Solubility (water): Insoluble |
| > 98 %, all 1,4-Dichlorobenzene | Percent Volatile: > 98 % |
Section 10. Stability and Reactivity
|
| Stability: Stable |
| Conditions to Avoid: None known |
| Incompatable Materials: None known |
| Hazardous Decomposition Products: None known |
| Possibility of Hazardous Reactions: None known |
Section 11. Toxicology Information
|
| ACCUTE EFFECTS | |
| Oral LD50: | 3790 mg/kg, rat |
| Dermal LD50: | 5000 mg/kg, rabbit |
| Inhalation: | 500 ppm, rat |
| Eye Irritation: | Direct contact with cake can irritate eyes |
| Skin Irritation: | Prolonged or repeated direct contact can irritate skin |
| Sensitization: | None known |
| CHRONIC EFFECTS | |
| Carcinogenicity: | NTP: B. Reasonably anticipated to be a carcinogen. IARC: 2B. Possible Carcinogen. |
| Mutagenicity: | None known |
| Reproductive Effects: | None known |
| Developmental Effects: | None known |
Section 12. Ecological Information
|
| Ecotoxicity: | None known |
| Persistence/Degradability: | Low biodegradability |
| Bioaccumulation/Accumulation: | Not determined |
| Mobility in Enviroment: | Not determined |
Section 13. Disposal Considerations
|
| Disposal: | Dispose according to all Federal, State or Provincial, and Local Regulations |
Section 14. Transportation Information |
| US DOT (ground) |
| Proper Shipping Description: Consumer Commodity - ORM-D |
| CANADA TDG (ground) |
| Proper Shipping Description: Not a Dangerous Good |
| ICAO (air) |
| Proper Shipping Description: Not a Dangerous Good in sizes offered |
| IMDG (water) |
| Proper Shipping Description: Not a Dangerous Good in sizes offered |
Section 15. Regulatory Information
|
| Global Inventories | |
| TSCA: United States | Included |
| DSL: Canada | Included |
| ECL: Korea | Not-Known |
| PICCS: Philippines | Not-Known |
| ENCS: Japan | Not-Known |
| AICS: Australia | Included |
| IECS: China | Not-Known |
| EINECS: European Union | Included |
| SARA 313 Information : | Sizes offered do not contain reportable levels of any SARA 313 substances. |
| California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65) | |
| 1,4-Dichorobenzene is considered a carcinogen under Proposition 65 | |
| WHMIS: Canadian Workplace Hazardous Material Information System | |
| D 2 B | |
Section 16. Other Information
|
| Legends: | |
| NFPA, HMIS: | |
| 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard | |
| Prepared By: | Technical Dept. |
| While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws. | |