MATERIAL SAFETY DATA SHEET
| Sheet No. 172 | Revision Date: 17 March 2010 |
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MATERIAL SAFETY DATA SHEET |
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| HMIS: Health- 2 Flammability- 3 Reactivity- 0 Pers. Protection- N |
NFPA: Health- 2 Flammability- 3 Reactivity- 0 Special Hazard- N |
WHMIS:
B 5 | ||
Section 1: Product and Company Identification |
Product: Nilotron Metered Flying Insect Spray
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Synonyms: |
| NILODOR, INC. | |
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA |
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Non-Emergency: |
24 hr Emergency Spill Information: |
US 800-443-4321
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Chem-Tel, Inc. |
International 010-330-874-1017
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US, Canada: 800-255-3924. International: 1-813-248-0584 |
Section 2. Hazards Identification
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| EMERGENCY OVERVIEW | |
| Appearance/Odor: | Colourless or pale yellow liquid in aerosol can |
| Classified as hazardous by the criteria of NOHSC. | |
| WARNING | |
| Flammability : | R 12: Contains compressed gas |
| Health Hazards Listed : Can irritate eyes and skin | |
| Ecological Hazards Listed : None known | |
| Potential Health Effects: See section 11 for more information. | |
| Likely Routes of Exposure: Inhalation | |
| Eye: | Direct exposure can irritate |
| Skin: | Repeated exposure may dry |
| Ingestion: | Unlikely due to form. Aspiration of liquid portion could cause chemical pneumonitis and nausea. |
| Inhalation: | May cause dizziness, headache, asphyxia |
| Medical Conditions Aggravated By Exposure: | |
| Allergies to fragrances | |
| Target Organs: | None known |
| This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. | |
| This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). | |
| Potential Environmental Effects: (See section 12 for more information.) | |
| None known | |
Section 3. Composition/Information on Ingredients
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| Component | CAS# | % by Weight | WHMIS Controlled |
| Isobutane / Propane Blend | 75-28-5 / 74-98-6 | 35-45 | N |
| Pyrethrum | 8003-34-7 | 0.1 - 1.0 | N |
| Piperonyl Butoxide | 51-03-6 | 1 - 5 | N |
| n-Octyl Bicycloheptenedicarboximide | 113-48-4 | 1 - 5 | N |
| Petroleum Distillates | 8052-41-3 | 30 - 50 | Y |
Section 4. First Aid Measures |
| Eye Contact: | Flush eyes with copious amounts of clean water. Consult physician if irritation persists. |
| Skin Contact: | Remove all contaminated clothing. Wash with soap and water for at least 15 minutes. Consult a physician. |
| Inhalation: | Remove to fresh air. Apply artificial respiration if needed. |
| Ingestion: | Not applicable due to form. If liquid or sprayed material is ingested, DO NOT induce vomiting or give liquids. Call physician or poison control center immediately. |
| Note to Physicians: |
Section 5. Fire Fighting Measures |
| Suitable Extinguishing Media: | Water spray, foam, dry chemical, carbon dioxide. HAZCHEM CODE 3 Y |
| Unsuitable Extinguishing Media: | None known |
| Products of Combustion: | Oxides of carbon and nitrogen |
| Protection of Firefighters: | Cans can burst if heated above 50°C/122°F. Recommend full protective gear including self-contained breathing apparatus. May spray cans to cool & reduce probability of bursting. |
Section 6. Accidental Release Measures
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| Personal Precautions: | Do not puncture or incinerate cans. Keep below 50°C/122°F |
| Environmental Precautions: | Keep liquids out of surface waters and sewers. |
| Methods for Containment: | Individual containers are low volume. No special measures |
| Methods for Clean-Up: | Gather up scattered cans after any breached cans have finished discharging. Absorb discharge on sand, clay or other suitable material. |
| Other Information: | HAZCHEM CODE 3 Y |
Section 7. Handling and Storage
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| HANDLING |
| Use as directed. Do not remove cap until ready to insert in dispenser. Do not puncture or incinerate “Empty” container. Keep below 50°C/122°F. |
| STORAGE |
| KEEP OUT OF REACH OF CHILDREN. Keep below 50°C/122°F. Storage in original box until ready to insert in dispenser is advised. |
Section 8. Exposure Controls/Personal Protection |
| EXPOSURE GUIDELINES | ||
| COMPONENT: | TWA: | LD-50 |
| Isobutane / Propane Blend | 1000 ppm | Simple asphyxiant |
| Pyrethrum | 5 mg/cubic meter | Not determined |
| Piperonyl Butoxide | None Established | 7500 mg/kg |
| n-Octyl Bicycloheptenedicarboximide | None Established | 4220 mg/kg |
| Petroleum Distillates | 100 ppm | 1000 mg/kg |
| Engineering Controls: Normal ventilation | ||
| Eye/Face Protection: Not needed when can is installed in dispenser. Safety glasses with side shields if discharging out of dispenser. | ||
| Skin Protection: Not needed when can is installed in dispenser. Neoprene gloves may be used if discharging out of dispenser. | ||
| Respiratory Protection: Not normally needed due to small quantities discharged. If vapor concentration exceeds TLV, use respirator for organic vapor. | ||
| General Hygiene Considerations: Keep away from food and beverages. | ||
Section 9. Physical and Chemical Properties
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| Color: Dispersed as fine colorless to pale yellow mist | Odor: Described by primary manufacturer as lime. Typical insecticide odor. |
| Physical State: Liquid and compressed gas in aerosol can | Odor Treshhold: |
| pH: Not applicable - non-aqueous | Freezing Point: Not determined |
| Evaporation Rate: Not determined | Boiling Point: Not applicable |
| Flash Point: Can can burst on prolonged exposure to temperatures of 55°C/130°F or higher, releasing flammable material | Flammability(solid,gas): Contents flammable. Product not a"Flammable Aerosol" as defined by IMO/ICAO |
| Upper Flammability Limit: Not determined | Lower Flammabilty Limit: Not determined |
| Vapor Pressure: PSIG @70F (Aerosols): 70-80 | Specific Gravity: Not applicable. Liquid portion approximately 6.59 Lb. Av. per U.S. Gallon at 20°C/68°F. (0.8 kg/L) |
| Vapor Density: Greater than air | Auto-ignition Temperature: Not determined |
| Volatile Organic Compound (VOC),%weight: | Solubility (water): Insoluble |
| Less than 24% by weight | Percent Volatile: Less than 24% by weight |
Section 10. Stability and Reactivity
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| Stability: Stable |
| Conditions to Avoid: Temperatures above 50°C/122°F, Direct sunlight, open flame, welding |
| Incompatable Materials: Acids, Alkalis |
| Hazardous Decomposition Products: CO, CO2 |
| Possibility of Hazardous Reactions: Will not occur |
Section 11. Toxicology Information
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| ACCUTE EFFECTS | |
| Oral LD50: | Not determined for mixture. Weighted average of liquid portion more than 950 mg/kg. |
| Dermal LD50: | Not determined for mixture. Weighted average of liquid portion more than 1000 mg/kg. |
| Inhalation: | Not determined for mixture. Weighted average more than 20 milligrams per Liter. |
| Eye Irritation: | Can irritate eyes if sprayed directly into eyes. |
| Skin Irritation: | Prolonged exposure to expelled liquid may result in irritation |
| Sensitization: | None known |
| CHRONIC EFFECTS | |
| Carcinogenicity: | None |
| Mutagenicity: | None |
| Reproductive Effects: | None |
| Developmental Effects: | None |
Section 12. Ecological Information
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| Ecotoxicity: | None known |
| Persistence/Degradability: | Biodegradable |
| Bioaccumulation/Accumulation: | Not significant |
| Mobility in Enviroment: | Not applicable due to mode of use |
Section 13. Disposal Considerations
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| Disposal: | Do not puncture or incinerate. Follow local regulations |
Section 14. Transportation Information |
| US DOT (ground) |
| Proper Shipping Description: Consumer Commodity - ORM-D |
| CANADA TDG (ground) |
| Proper Shipping Description: Commodity - ORM-D |
| ICAO (air) |
| Proper Shipping Description: UN 1950,Aerosols, non-flammable, Class 2.2, LTD QTY |
| IMDG (water) |
| Proper Shipping Description: UN 1950,Aerosols, non-flammable, Class 2.2, EMS- F-D, S-U, LTD QTY |
Section 15. Regulatory Information
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| Global Inventories | |
| TSCA: United States | Included |
| DSL: Canada | Included |
| ECL: Korea | Not-Known |
| PICCS: Philippines | Not-Known |
| ENCS: Japan | Not-Known |
| AICS: Australia | Included |
| IECS: China | Not-Known |
| EINECS: European Union | Included |
| SARA 313 Information : | No Sara 313 Listed substances present at reportable levels |
| California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65) | |
| No Proposition 65 Listed substences present | |
| WHMIS: Canadian Workplace Hazardous Material Information System | |
| B 5 | |
Section 16. Other Information
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| EPA Registration 10807-44-27053 EPA Establishment No. 10807-GA-1 | |
| Legends: | |
| NFPA, HMIS: | |
| 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard | |
| Prepared By: | Technical Dept. |
| While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws. | |