Sheet No. 318
Revision Date: 13 May 2010
SMSUPERN
Nilodor-msds
Certified
MATERIAL SAFETY DATA SHEET
HMIS:
Health- 2 Flammability- 2 Reactivity- 0 Pers. Protection- N
NFPA:
Health- 2 Flammability- 2 Reactivity- 0 Special Hazard- N
WHMIS: B 3, D 2 B
Section 1: Product and Company Identification
Product: Big Wick, Natural
Synonyms:
NILODOR, INC.  
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA

Non-Emergency:

24 hr Emergency Spill Information:
US 800-443-4321
Chem-Tel, Inc.
International 010-330-874-1017
US, Canada: 800-255-3924. International: 1-813-248-0584
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: Yellow liquid, spicy aroma with vanilla tones
Classified as hazardous by the criteria of NOHSC.
WARNING  
Flammability : Combustible
Health Hazards Listed : R 65: Harmful. May cause lung damage if swallowed and aspirated.
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.
Likely Routes of Exposure: Skin, eyes
Eye: Direct exposure can irritate
Skin: Prolonged or repeated exposure can irritate
Ingestion: Not expected to be a problem
Inhalation: Not likely to be a problem
Medical Conditions Aggravated By Exposure:
Allergies to fragrances
Target Organs: None known
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
Component CAS# % by Weight WHMIS Controlled
Cinnamaldehyde 104-55-2 10 - 30 Y
Vanillin 121-33-5 7 - 13 N
Trade Secret Fragrance Mixture, not otherwise spec None 30 - 60 N
n-Pentyl Acetate 628-63-7 5-10 Y
Methyl Salicylate 119-36-8 5-10 Y
d-Limonene 5989-27-5 5-10 Y
Section 4. First Aid Measures
Eye Contact: Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air.
Ingestion: Give water or milk to drink if conscious.
Note to Physicians: Contains fragrance oils. Induction of vomiting is NOT recommended. If needed, gastric lavage may be used.
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Water, foam, carbon dioxide, dry chemical
Unsuitable Extinguishing Media: None known
Products of Combustion: Oxides of carbon, nitrogen, sulfur
Protection of Firefighters: As for surrounding fire
Section 6. Accidental Release Measures
Personal Precautions: Keep away from skin and eyes
Environmental Precautions: Keep out of surface waters
Methods for Containment: Dike with sand, clay or other suitable material.
Methods for Clean-Up: Absorb on sand, clay or other suitable material.
Other Information:
Section 7. Handling and Storage
HANDLING
Reasonable care. Keep away from skin and eyes.
STORAGE
Closed original containers at ambient conditions (5-50°C; 40 - 120°F)
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES  
COMPONENT: TWA: LD-50
Cinnamaldehyde None established 2220 mg/kg
Vanillin None established 1580 mg/kg
Trade Secret Fragrance Mixture, not otherwise spec None established Not determined
n-Pentyl Acetate 50 ppm 14000 mg/kg
Methyl Salicylate None established 887 mg/kg
d-Limonene None established 4400 mg/kg
Engineering Controls: Normal ventilation
Eye/Face Protection: Protective goggles recommended if handling large quantities.
Skin Protection: Rubber or other protective gloves recommended if handling large quantities.
Respiratory Protection: Not normally necessary.
General Hygiene Considerations: Keep out of food and beverages.
Section 9. Physical and Chemical Properties
Color: Yellow Odor: Characteristic spicy/vanilla aroma
Physical State: Liquid Odor Treshhold:
pH: Not applicable Freezing Point: Not determined
Evaporation Rate: Slower than water Boiling Point: more than 100°C/212°F
Flash Point: 57°C/139°F PMCC Flammability(solid,gas): Not applicable
Upper Flammability Limit: Not determined Lower Flammabilty Limit: Not determined
Vapor Pressure: Not determined Specific Gravity: 0.99
Vapor Density: Not determined Auto-ignition Temperature: Not determined.
Volatile Organic Compound (VOC),%weight: Solubility (water): Insoluble.
All fragrance Percent Volatile: Less than 65%
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: None known
Incompatable Materials: None known
Hazardous Decomposition Products: None known
Possibility of Hazardous Reactions: Extremely improbable
Section 11. Toxicology Information
ACCUTE EFFECTS
Oral LD50: Not determined for mixture. Weighted average more than 1500 mg/kg.
Dermal LD50: Not classified as toxic by skin contact. Not determined for mixture. Weighted average more than 1100 mg/kg.
Inhalation: Not classified as toxic by inhalation. Not determined for mixture. Weighted average more than 3 mg/L.
Eye Irritation: Direct contact is irritating. If eyes are not rinsed immediately, irritation can become severe.
Skin Irritation: Prolonged or repeated contact can irritate or dry skin.
Sensitization: None known
CHRONIC EFFECTS
Carcinogenicity: None known
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: None known
Persistence/Degradability: Biodegradable
Bioaccumulation/Accumulation: None known
Mobility in Enviroment: Not determined
Section 13. Disposal Considerations
Disposal: Dispose according to Federal, State or Provincial,and Local regulations.
Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Not Regulated
CANADA TDG (ground)
Proper Shipping Description: Not Regulated
ICAO (air)
Proper Shipping Description: Extracts, Aromatic, Liquid Class 3 UN1169 Packaging Group III, Limited Quantity
IMDG (water)
Proper Shipping Description: Extracts, Aromatic, Liquid Class 3 UN1169 Packaging Group III EmS Codes F-E, S-D, Limited Quantity
Section 15. Regulatory Information
Global Inventories  
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included
   
SARA 313 Information : No SARA 313 substances present at reportable levels
 
California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
No Proposition 65 substances present
WHMIS: Canadian Workplace Hazardous Material Information System
B 3, D 2 B
Section 16. Other Information
Legends:  
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard
   
Prepared By: Technical Dept.
   
While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws.