MATERIAL SAFETY DATA SHEET
| Sheet No. 328 | Revision Date: 29 August 2008 |
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MATERIAL SAFETY DATA SHEET |
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| HMIS: Health- 1 Flammability- 1 Reactivity- 0 Pers. Protection- |
NFPA: Health- 1 Flammability- 1 Reactivity- 0 Special Hazard- |
WHMIS:
B 5 | ||
Section 1: Product and Company Identification |
Product: Doctor Spot
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Synonyms: VOC Compliant aerosol spotter |
| NILODOR, INC. | |
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA |
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Non-Emergency: |
24 hr Emergency Spill Information: |
US 800-443-4321
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Chem-Tel, Inc. |
International 010-330-874-1017
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US, Canada: 800-255-3924. International: 1-813-248-0584 |
Section 2. Hazards Identification
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| EMERGENCY OVERVIEW | |
| Appearance/Odor: | Liquid under pressurized gas in steel can |
| NOT Classified as hazardous by the criteria of NOHSC. | |
| WARNING | |
| Flammability : | Considered to be non-flammable |
| Health Hazards Listed : May be a mild irritant | |
| Ecological Hazards Listed : None known | |
| Potential Health Effects: See section 11 for more information. | |
| Likely Routes of Exposure: Skin, eyes | |
| Eye: | Direct exposure can irritate |
| Skin: | Prolonged exposure can irritate |
| Ingestion: | Not expected to be a problem |
| Inhalation: | Not likely to be a problem |
| Medical Conditions Aggravated By Exposure: | |
| Allergies to fragrances | |
| Target Organs: | None known |
| This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. | |
| This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). | |
| Potential Environmental Effects: (See section 12 for more information.) | |
| None known | |
Section 3. Composition/Information on Ingredients
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| Component | CAS# | % by Weight | WHMIS Controlled |
| d-Limonene | 5989-27-5 | Y | |
| Liquefied Petroleum Gas | 68476-86-8 | Y | |
| 2- Propanol | 67-63-0 | Y | |
| Ethylene Glycol Monobutyl Ether | 111-76-2 | Y |
Section 4. First Aid Measures |
| Eye Contact: | Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician. |
| Skin Contact: | Wash with soap and water. |
| Inhalation: | Remove to fresh air. |
| Ingestion: | Contact poison control for advice on whether to induce vomiting. |
| Note to Physicians: |
Section 5. Fire Fighting Measures |
| Suitable Extinguishing Media: | Carbon dioxide, dry chemical. Water spray may be used to cool cans to reduce risk of bursting. HAZCHEM CODE 3 [Y] |
| Unsuitable Extinguishing Media: | None known |
| Products of Combustion: | Oxides of carbon and nitrogen. |
| Protection of Firefighters: | Try to keep cans below 50°C / 120 F |
Section 6. Accidental Release Measures
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| Personal Precautions: | Keep away from skin and eyes |
| Environmental Precautions: | Keep spray or punctured cans out of surface waters |
| Methods for Containment: | Not applicable: if cans rupture or are punctured, contents will rapidly evaporate |
| Methods for Clean-Up: | Gather up scattered cans after any punctured cans have finished discharging. Absorb any discharge on sand, clay or other suitable material. |
| Other Information: | Do not puncture or incinerate cans. |
Section 7. Handling and Storage
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| HANDLING |
| Reasonable care. Avoid puncturing cans; keep spray away from skin and eyes. |
| STORAGE |
| Keep out of the reach of children. Store in original cartons at temperatures not more than 55°C |
Section 8. Exposure Controls/Personal Protection |
| EXPOSURE GUIDELINES | ||
| COMPONENT: | TWA: | LD-50 |
| d-Limonene | None established | 5600 mg/kg |
| Liquefied Petroleum Gas | 1000 ppm TLV | 350 mg/kg |
| 2- Propanol | 400 ppm | 5045 mg/kg |
| Ethylene Glycol Monobutyl Ether | 50 ppm | 1480 mg/kg |
| Engineering Controls: Normally not necessary | ||
| Eye/Face Protection: Be careful not to spray in direction of face. Protective goggles recommended if handling large quantities | ||
| Skin Protection: Avoid spraying on skin. Rubber or other protective gloves recommended if handling large quantities. | ||
| Respiratory Protection: Not normally necessary. | ||
| General Hygiene Considerations: Keep spray out of food and beverages | ||
Section 9. Physical and Chemical Properties
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| Color: Colourless to pale yellow | Odor: Mild citrus |
| Physical State: Liquid under compressed gas in steel can | Odor Treshhold: |
| pH: 9.5-10.5 | Freezing Point: Not determined |
| Evaporation Rate: < 1.00 | Boiling Point: >200 F, cans may explode higher than 120 F |
| Flash Point: Not applicable. Cans can burst if heated to temperatures above 55°C. | Flammability(solid,gas): NA |
| Upper Flammability Limit: Not determined | Lower Flammabilty Limit: Not determined |
| Vapor Pressure: NA | Specific Gravity: 0.98-1.00 |
| Vapor Density: Not determined | Auto-ignition Temperature: Not determined |
| Volatile Organic Compound (VOC),%weight: | Solubility (water): Soluble |
| 23.2% | Percent Volatile: 23.2 |
Section 10. Stability and Reactivity
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| Stability: Stable |
| Conditions to Avoid: Temperatures above 55°C / 120F |
| Incompatable Materials: Strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, volatile hydrocarbons |
| Hazardous Decomposition Products: None known |
| Possibility of Hazardous Reactions: Extremely improbable |
Section 11. Toxicology Information
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| ACCUTE EFFECTS | |
| Oral LD50: | Not determined for mixture. |
| Dermal LD50: | Product dispersed as fine mist. |
| Inhalation: | Not determined for mixture. |
| Eye Irritation: | Direct contact can irritate eyes |
| Skin Irritation: | Prolonged direct contact with spray can dry or irritate skin |
| Sensitization: | None known |
| CHRONIC EFFECTS | |
| Carcinogenicity: | None known |
| Mutagenicity: | None known |
| Reproductive Effects: | None known |
| Developmental Effects: | None known |
Section 12. Ecological Information
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| Ecotoxicity: | None known |
| Persistence/Degradability: | None known |
| Bioaccumulation/Accumulation: | None known |
| Mobility in Enviroment: | Not determined |
Section 13. Disposal Considerations
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| Disposal: | Do not puncture or incinerate cans. Dispose according to Federal, State and Local regulations |
Section 14. Transportation Information |
| US DOT (ground) |
| Proper Shipping Description: Consumer Commodity - ORM-D |
| CANADA TDG (ground) |
| Proper Shipping Description: Consumer Commodity - ORM-D |
| ICAO (air) |
| Proper Shipping Description: UN1950, Aerosols, Flammable, Class 2.1, LTD QTY |
| IMDG (water) |
| Proper Shipping Description: UN1950, Aerosols, Flammable, Class 2.1, EmS F-D, S-U, LTD QTY |
Section 15. Regulatory Information
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| Global Inventories | |
| TSCA: United States | Included |
| DSL: Canada | Included |
| ECL: Korea | Not-Known |
| PICCS: Philippines | Not-Known |
| ENCS: Japan | Not-Known |
| AICS: Australia | Included |
| IECS: China | Not-Known |
| EINECS: European Union | Included |
| SARA 313 Information : | No SARA 313 substances present at reportable levels |
| California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65) | |
| No Proposition 65 substances present | |
| WHMIS: Canadian Workplace Hazardous Material Information System | |
| B 5 | |
Section 16. Other Information
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| Legends: | |
| NFPA, HMIS: | |
| 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard | |
| Prepared By: | Technical Dept. |
| While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws. | |