MATERIAL SAFETY DATA SHEET
| Sheet No. 35 | Revision Date: 20 June 2008 |
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MATERIAL SAFETY DATA SHEET |
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| HMIS: Health- 1 Flammability- 2 Reactivity- 0 Pers. Protection- N |
NFPA: Health- 1 Flammability- 2 Reactivity- 0 Special Hazard- N |
WHMIS:
D 2 B | ||
Section 1: Product and Company Identification |
Product: Chlorinated Nilogel
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Synonyms: Nilogel, Chlorinated |
| NILODOR, INC. | |
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA |
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Non-Emergency: |
24 hr Emergency Spill Information: |
US 800-443-4321
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Chem-Tel, Inc. |
International 010-330-874-1017
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US, Canada: 800-255-3924. International: 1-813-248-0584 |
Section 2. Hazards Identification
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| EMERGENCY OVERVIEW | |
| Appearance/Odor: | Yellowish powder |
| Classified as hazardous by the criteria of NOHSC. | |
| WARNING | |
| Flammability : | Not classified as flammable |
| Health Hazards Listed : R 36: Irritating to eyes. (No R code listed): contact with alkaline materials can liberate toxic gas | |
| Ecological Hazards Listed : None known | |
| Potential Health Effects: See section 11 for more information. | |
| Likely Routes of Exposure: Not applicable | |
| Eye: | Direct exposure can irritate |
| Skin: | Prolonged or repeated exposure can irritate |
| Ingestion: | Can irritate digestive tract |
| Inhalation: | Not applicable |
| Medical Conditions Aggravated By Exposure: | |
| Allergies to fragrances | |
| Target Organs: | None known |
| This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. | |
| This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). | |
| Potential Environmental Effects: (See section 12 for more information.) | |
| None known | |
Section 3. Composition/Information on Ingredients
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| Component | CAS# | % by Weight | WHMIS Controlled |
| Starch | 9005-25-8 | 10 - 30 | N |
| Calcium Hypochlorite | 7778-54-3 | 0.5 - 1.5 | N |
| Methyl Salicylate | 119-36-8 | 0.1 - 1.0 | Y |
| Cinnamaldehyde | 104-55-2 | 0.1 - 1.0 | Y |
| Sodium Polyacrylate | 9003-04-7 | 40 - 70 | N |
Section 4. First Aid Measures |
| Eye Contact: | Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician. |
| Skin Contact: | Wash with soap and water. |
| Inhalation: | Remove to fresh air. |
| Ingestion: | Do NOT induce vomiting. If conscious, give milk or water to drink. |
| Note to Physicians: | Contact with alkaline liquids can liberate chlorine. |
Section 5. Fire Fighting Measures |
| Suitable Extinguishing Media: | Water, foam, dry chemical |
| Unsuitable Extinguishing Media: | None known |
| Products of Combustion: | Oxides of carbon and nitrogen, possible chlorine, hydrogen chloride, chlorine oxides |
| Protection of Firefighters: | If large amounts of product involved, self-contained breathing apparatus |
Section 6. Accidental Release Measures
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| Personal Precautions: | Avoid skin and eye contact. |
| Environmental Precautions: | Keep out of surface waters |
| Methods for Containment: | Surround with sand, clay or other material. |
| Methods for Clean-Up: | Sweep, scoop or shovel up for disposal. |
| Other Information: | Exposure to acids can liberate chlorine gas |
Section 7. Handling and Storage
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| HANDLING |
| Keep dry. |
| STORAGE |
| Keep out of reach of children. Keep in original container at ambient temperatures (below 50°C/122°F) |
Section 8. Exposure Controls/Personal Protection |
| EXPOSURE GUIDELINES | ||
| COMPONENT: | TWA: | LD-50 |
| Starch | Not applicable | Not applicable |
| Calcium Hypochlorite | None established | 850 mg/kg |
| Methyl Salicylate | None established | 887 mg/kg |
| Cinnamaldehyde | None established | 2220 mg/kg |
| Sodium Polyacrylate | None established | Not determined |
| Engineering Controls: Not normally necessary | ||
| Eye/Face Protection: Protective goggles if handling large quantities | ||
| Skin Protection: Rubber or other protective gloves if handling large quantities | ||
| Respiratory Protection: Not normally necessary, but see section 10 | ||
| General Hygiene Considerations: Reasonable care. Keep away from food and beverages | ||
Section 9. Physical and Chemical Properties
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| Color: Yellowish white | Odor: Spicy |
| Physical State: Powder | Odor Treshhold: |
| pH: Not applicable | Freezing Point: Not applicable |
| Evaporation Rate: Not applicable | Boiling Point: Not applicable |
| Flash Point: Not applicable | Flammability(solid,gas): Will burn if ignited, but not classified as a flammable solid |
| Upper Flammability Limit: Not determined | Lower Flammabilty Limit: Not determined |
| Vapor Pressure: Less than 0.01 torr at 20°C | Specific Gravity: Not applicable. |
| Vapor Density: Not applicable | Auto-ignition Temperature: Not determined |
| Volatile Organic Compound (VOC),%weight: | Solubility (water): Absorbs up to 100 times its own mass of water. Larger amounts of water form flushable slurries |
| Less than 5%, all fragrance | Percent Volatile: Less than 5%, all fragrance |
Section 10. Stability and Reactivity
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| Stability: Stable under normal conditions |
| Conditions to Avoid: Exposure to alkaline materials |
| Incompatable Materials: Alkaline materials |
| Hazardous Decomposition Products: Chlorine gas on contact with alkaline materials |
| Possibility of Hazardous Reactions: See above |
Section 11. Toxicology Information
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| ACCUTE EFFECTS | |
| Oral LD50: | Not evaluated as a mixture. Weighted average more than 1200 mg/kg. |
| Dermal LD50: | Not evaluated as a mixture. Weighted average more than 2000 mg/kg. |
| Inhalation: | Not evaluated as a mixture. Weighted average more than 3 milligrams per liter. |
| Eye Irritation: | Direct contact is irritating |
| Skin Irritation: | Prolonged contact can irritate |
| Sensitization: | None known |
| CHRONIC EFFECTS | |
| Carcinogenicity: | None known |
| Mutagenicity: | None known |
| Reproductive Effects: | None known |
| Developmental Effects: | None known |
Section 12. Ecological Information
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| Ecotoxicity: | Not applicable |
| Persistence/Degradability: | Mostly biodegradable |
| Bioaccumulation/Accumulation: | Not applicable |
| Mobility in Enviroment: | Not applicable |
Section 13. Disposal Considerations
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| Disposal: | Dispose in accordance with Federal, State or Provincial and Local regulations |
Section 14. Transportation Information |
| US DOT (ground) |
| Proper Shipping Description: Not a Hazardous Material |
| CANADA TDG (ground) |
| Proper Shipping Description: Not a Dangerous Good |
| ICAO (air) |
| Proper Shipping Description: Not a Dangerous Good |
| IMDG (water) |
| Proper Shipping Description: Not a Dangerous Good |
Section 15. Regulatory Information
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| Global Inventories | |
| TSCA: United States | Included |
| DSL: Canada | Included |
| ECL: Korea | Not-Known |
| PICCS: Philippines | Not-Known |
| ENCS: Japan | Not-Known |
| AICS: Australia | Included |
| IECS: China | Not-Known |
| EINECS: European Union | Included |
| SARA 313 Information : | No SARA 313 chemicals present at reportable levels |
| California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65) | |
| No Proposition 65 substances present | |
| WHMIS: Canadian Workplace Hazardous Material Information System | |
| D 2 B | |
Section 16. Other Information
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| Legends: | |
| NFPA, HMIS: | |
| 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard | |
| Prepared By: | Technical Dept. |
| While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws. | |