Sheet No. 373
Revision Date: 21 January 2009
SMSUPERN
Nilodor-msds
Certified
MATERIAL SAFETY DATA SHEET
HMIS:
Health- 1 Flammability- 0 Reactivity- 0 Pers. Protection- B
NFPA:
Health- 1 Flammability- 0 Reactivity- 0 Special Hazard- N
WHMIS: D 2 B
Section 1: Product and Company Identification
Product: Plant Detergent
Synonyms:
NILODOR, INC.  
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA

Non-Emergency:

24 hr Emergency Spill Information:
US 800-443-4321
Chem-Tel, Inc.
International 010-330-874-1017
US, Canada: 800-255-3924. International: 1-813-248-0584
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: White/pale yellow powder, citrus aroma
NOT Classified as hazardous by the criteria of NOHSC.
WARNING  
Flammability : Not classified as flammable
Health Hazards Listed : R 36: Irritating to eyes.
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.
Likely Routes of Exposure: Eyes, mouth
Eye: Direct exposure can irritate
Skin: Prolonged or repeated exposure can irritate
Ingestion: Can cause digestive distress
Inhalation: Dust can irritate
Medical Conditions Aggravated By Exposure:
Allergies to fragrances
Target Organs: None known
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
Component CAS# % by Weight WHMIS Controlled
Sodium Carbonate 497-19-8 40 - 60 Y
Non-ionic surfactant 9036-19-5 5-10 Y
Sodium Borate 1303-96-4 7 - 13 Y
Sodium Metasilicate 6834-92-0 5-10 Y
Water 7732-18-5 5-10 N
Section 4. First Aid Measures
Eye Contact: Flush eye with copious amounts of clean water,holding lids open. If irritation persists get medical attention.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air.
Ingestion: If conscious, give water or milk to drink. DO NOT INDUCE VOMITING.
Note to Physicians: Product dissolves in water to form alkaline solution. Prolonged contact can severely irritate eyes and respiratory tract and can dry or irritate skin.
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Water, foam, carbon dioxide, dry chemical.
Unsuitable Extinguishing Media: None known.
Products of Combustion: Oxides of carbon, boron, nitrogen.
Protection of Firefighters: Self-contained breathing apparatus if large quantities are involved.
Section 6. Accidental Release Measures
Personal Precautions: Keep away from eyes and mouth. Avoid breathing dust.
Environmental Precautions: Keep out of surface waters and sanitary sewers.
Methods for Containment: Powder, not applicable. Solutions: dike area with sand, clay or other suitable material.
Methods for Clean-Up: Sweep, shovel or scoop up powder for disposal. Absorb solutions on sand, clay or other suitable material or mop up with water.
Other Information:
Section 7. Handling and Storage
HANDLING
Do not open until ready to use.
STORAGE
Keep out of the reach of children. Store in original container at ambient conditions.
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES  
COMPONENT: TWA: LD-50
Sodium Carbonate Dust 10 mg/cubic meter 4090 mg/kg
Non-ionic surfactant None established 707 mg/kg
Sodium Borate 5 mg/cubic meter >4500 mg/kg
Sodium Metasilicate Dust 10 mg/cubic meter > 1500 mg/kg
Water None established Not applicable
Engineering Controls: Not normally necessary.
Eye/Face Protection: Protective goggles if handling large quantities.
Skin Protection: Rubber or other protective gloves if handling large quantities.
Respiratory Protection: Dust mask or particulates respirator recommended.
General Hygiene Considerations: Reasonable care. Keep away from food and beverages.
Section 9. Physical and Chemical Properties
Color: White to pale yellow Odor: Mild citrus
Physical State: Powder Odor Treshhold:
pH: 8.5 - 10.5, 0.1% solution Freezing Point: Not applicable
Evaporation Rate: Not applicable Boiling Point: Not applicable
Flash Point: Not applicable Flammability(solid,gas): Non-flammable
Upper Flammability Limit: Not applicable Lower Flammabilty Limit: Not applicable
Vapor Pressure: Not determined Specific Gravity: Bulk density more than 0.65 g/mL, tapped
Vapor Density: Not determined Auto-ignition Temperature: Not applicable
Volatile Organic Compound (VOC),%weight: Solubility (water): Minimum 0.35 %
0.1% Percent Volatile: Less than 20% including water of crystallization
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: High temperatures
Incompatable Materials: Strong acids
Hazardous Decomposition Products: None known
Possibility of Hazardous Reactions: Very improbable
Section 11. Toxicology Information
ACCUTE EFFECTS
Oral LD50: Not determined for mixture. Weighted average more than 2900 mg/kg
Dermal LD50: Weighted average more than 1000 mg/kg.
Inhalation: Low volatility. Weighted average as dusts more than 2.5 milligrams per Liter.
Eye Irritation: Direct contact can be severely irritating
Skin Irritation: Prolonged or repeated contact can dry or irritate skin.
Sensitization: None known
CHRONIC EFFECTS
Carcinogenicity: None known
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: Not determined.
Persistence/Degradability: Biodegradable.
Bioaccumulation/Accumulation: Not determined.
Mobility in Enviroment: Not determined.
Section 13. Disposal Considerations
Disposal: Dispose according to Federal, State or Provincial, and Local regulations.
Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Not a Hazardous Material
CANADA TDG (ground)
Proper Shipping Description: Not a Dangerous Good
ICAO (air)
Proper Shipping Description: Not a Dangerous Good
IMDG (water)
Proper Shipping Description: Not a Dangerous Good
Section 15. Regulatory Information
Global Inventories  
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included
   
SARA 313 Information : Does not contain any SARA 313 substances
 
California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
Does not contain any Proposition 65 substances
WHMIS: Canadian Workplace Hazardous Material Information System
D 2 B
Section 16. Other Information
Legends:  
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard
   
Prepared By: Technical Dept.
   
While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws.