Sheet No. 446
Revision Date: 20 June 2011
SMSUPERN
Nilodor-msds
Certified
MATERIAL SAFETY DATA SHEET
HMIS:
Health- 1 Flammability- 1 Reactivity- 0 Pers. Protection- B
NFPA:
Health- 1 Flammability- 1 Reactivity- 0 Special Hazard- N
WHMIS: B 5
Section 1: Product and Company Identification
Product: Foaming Pet Stain & Odor Remover
Synonyms:
NILODOR, INC.  
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA

Non-Emergency:

24 hr Emergency Spill Information:
US 800-443-4321
Chem-Tel, Inc.
International 010-330-874-1017
US, Canada: 800-255-3924. International: 1-813-248-0584
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: Liquid under pressurized gas in steel can
Classified as hazardous by the criteria of NOHSC.
WARNING  
Flammability : R 12 Extremely flammable. Contains pressurized gas.
Health Hazards Listed : May be a mild irritant
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.
Likely Routes of Exposure: Skin, eyes
Eye: Direct exposure can irritate
Skin: Prolonged exposure can irritate
Ingestion: Not expected to be a problem
Inhalation: Not likely to be a problem
Medical Conditions Aggravated By Exposure:
Allergies to fragrances
Target Organs: None known
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
Component CAS# % by Weight WHMIS Controlled
Propane 74-98-6 1 - 5 Y
Butane 106-97-8 3 - 7 Y
Ethanol 64-17-5 0.1 - 1 Y
Dipropylene Glycol 25265-71-8 1 - 5 N
Water 7732-18-5 80 - 100 N
Section 4. First Aid Measures
Eye Contact: Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air.
Ingestion: Give water or milk to drink if conscious.
Note to Physicians:
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Carbon dioxide, dry chemical. Water spray may be used to cool cans to reduce risk of bursting. HAZCHEM CODE 3 [Y]
Unsuitable Extinguishing Media: None known
Products of Combustion: Oxides of carbon and nitrogen.
Protection of Firefighters: Try to keep cans below 50°C/120°F
Section 6. Accidental Release Measures
Personal Precautions: Keep away from skin and eyes
Environmental Precautions: Keep spray or punctured cans out of surface waters
Methods for Containment: Not applicable: if cans rupture or are punctured, contents will rapidly evaporate
Methods for Clean-Up: Gather up scattered cans after any punctured cans have finished discharging. Absorb any discharge on sand, clay, or other suitable material or mop with water.
Other Information: Do not puncture or incinerate cans.
Section 7. Handling and Storage
HANDLING
Reasonable care. Avoid puncturing cans; keep spray away from skin and eyes.
STORAGE
Keep out of the reach of children. Store in original cartons at temperatures not more than 55°C/130°F
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES  
COMPONENT: TWA: LD-50
Propane TLV 1000 ppm Simple asphyxiant
Butane TLV 1000 ppm Simple asphyxiant
Ethanol 1000 ppm 7060 mg/kg
Dipropylene Glycol None Established 14800 mg/kg
Water None established Not applicable
Engineering Controls: Normally not necessary
Eye/Face Protection: Be careful not to spray in direction of face. Protective goggles recommended if handling large quantities
Skin Protection: Avoid spraying on skin. Rubber or other protective gloves recommended if handling large quantities.
Respiratory Protection: Not normally necessary.
General Hygiene Considerations: Keep spray out of food and beverages
Section 9. Physical and Chemical Properties
Color: Colourless to pale yellow. Foams when sprayed onto surface. Odor: Little if any.
Physical State: Liquid under compressed gas in steel can Odor Treshhold:
pH: Liquid fraction 7 - 8 Freezing Point: Not determined
Evaporation Rate: Not determined. Boiling Point: Not applicable. Cans can burst if heated to temperatures above 55°C/130°F.
Flash Point: Not applicable. Cans can burst if heated to temperatures above 55°C/130°F. Flammability(solid,gas): Classified as a ""Non-Flammable Aerosol"". Contents flammable due to presence of propellant gas.
Upper Flammability Limit: Not determined Lower Flammabilty Limit: Not determined
Vapor Pressure: Greater than 760 Torr at 20°C/68°F Specific Gravity: Not applicable.
Vapor Density: Not determined Auto-ignition Temperature: Not determined
Volatile Organic Compound (VOC),%weight: Solubility (water): Insoluble
< 15 including propellant Percent Volatile: 80 - 100
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: Temperatures above 55°C/130°C
Incompatable Materials: None known
Hazardous Decomposition Products: None known
Possibility of Hazardous Reactions: Extremely improbable
Section 11. Toxicology Information
ACCUTE EFFECTS
Oral LD50: Not determined for mixture. Liquid portion weighted average more than 40 grams per kilogram, rat.
Dermal LD50: Product dispersed as fine mist. Liquid portion weighted average more than 40 grams per kilogram, rabbit.
Inhalation: Not determined for mixture. Weighted average more than 30 milligrams per liter.
Eye Irritation: Direct contact can irritate eyes
Skin Irritation: Prolonged direct contact with spray can dry or irritate skin
Sensitization: None known
CHRONIC EFFECTS
Carcinogenicity: None known
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: None known
Persistence/Degradability: None known
Bioaccumulation/Accumulation: None known
Mobility in Enviroment: Not determined
Section 13. Disposal Considerations
Disposal: Do not puncture or incinerate cans. Dispose according to Federal, State and Local regulations
Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Consumer Commodity - ORM-D
CANADA TDG (ground)
Proper Shipping Description: Consumer Commodity - ORM-D
ICAO (air)
Proper Shipping Description: UN1950, Aerosols, Non-Flammable, Class 2.2, LTD QTY
IMDG (water)
Proper Shipping Description: UN1950, Aerosols, Non-Flammable, Class 2.2, EmS F-D, S-U, LTD QTY
Section 15. Regulatory Information
Global Inventories  
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included
   
SARA 313 Information : No SARA 313 substances present at reportable levels
 
California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
No Proposition 65 substances present
WHMIS: Canadian Workplace Hazardous Material Information System
B 5
Section 16. Other Information
Legends:  
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard
   
Prepared By: Technical Dept.
   
While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws.