Sheet No. 53
Revision Date: 26 May 2010
SMSUPERN
Nilodor-msds
Certified
MATERIAL SAFETY DATA SHEET
HMIS:
Health- 1 Flammability- 0 Reactivity- 0 Pers. Protection- N 		NFPA:
Health- 1 Flammability- 0 Reactivity- 0 Special Hazard- N
WHMIS: D 2 B
Section 1: Product and Company Identification
Product: Nilodew Dumpster Deodorizer NEW AND IMPROVED
 Synonyms:
NILODOR, INC.  
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA

Non-Emergency:

24 hr Emergency Spill Information:
US 800-443-4321
 Chem-Tel, Inc.
International 010-330-874-1017
 US, Canada: 800-255-3924. International: 1-813-248-0584
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: Gray-brown granules
NOT Classified as hazardous by the criteria of NOHSC.
WARNING  
Flammability : Not classified as flammable
Health Hazards Listed : Sensitivity to dust inhalation
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.
Likely Routes of Exposure: Respiration
Eye: Direct exposure may irritate
Skin: Prolonged or repeated exposure may irritate
Ingestion: Not expected to be a problem
Inhalation: Classified as Group 3 (not classifiable for human) by IARC
Medical Conditions Aggravated By Exposure:
Allergies to fragrances; Asthma or preexisting respiratory problems
Target Organs: Lungs, see below
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
Component CAS# % by Weight WHMIS Controlled
Clinoptilolite (Natural Zeolite) 1318-02-1 30-35 N
Water 7732-18-5 10-15 N
Silica: Quartz 14808-60-7 0-4 Y
Odor Counteractant NA 4-5 N
Montmorillonite Clay (Calcined) 70892-59-0 40-50 Y
Section 4. First Aid Measures
Eye Contact: Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air if irritation, cough, shortness of breath occurs.
Ingestion: Give water or milk to drink if conscious.
Note to Physicians: Inhalation of fragrance is not expected to be a problem. Inhalation of dry dust may cause discomfort to allergies / sensitivities
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Foam, carbon dioxide, dry chemical
Unsuitable Extinguishing Media: Fragrance portion could float on surface of water and continue burning
Products of Combustion: Oxides of carbon and nitrogen.
Protection of Firefighters: Due to residual silica, self-contained breathing apparatus or dust mask is recommended
Section 6. Accidental Release Measures
Personal Precautions: Keep away from skin and eyes. If product appears dry or dusty, wear dust mask or respirator.
Environmental Precautions: Keep out of surface waters and sanitary sewers.
Methods for Containment: No special requirements. Liquid portion is adsorbed on mineral carrier.
Methods for Clean-Up: Sweep up or shovel up for disposal.
Other Information: After granular powder has been swept or shoveled up, area of spill may be mopped with soap and water.
Section 7. Handling and Storage
HANDLING
Keep away from skin and eyes. If product is dry or dusty, wear dust mask or respirator.
STORAGE
Original container at ambient temperatures (below 60°C/140°F)
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES  
COMPONENT: TWA: LD-50
Clinoptilolite (Natural Zeolite) NA NA
Water NA NA
Silica: Quartz TLV 10 mg/cu m (0.0008% respirable) Not determined
Odor Counteractant NA NA
Montmorillonite Clay (Calcined) TLV 3 mg/ m3 NA
Engineering Controls: Normal Ventilation
Eye/Face Protection: Remove contact lenses (due to possible dust), Flush eyes with water if irritation occurs.
Skin Protection: Wash with soap and water. If sensitive skin, wear protective gloves.
Respiratory Protection: Dust mask or respirator recommended, especially if product appears dry or dusty. If inhaled remove to fresh air.
General Hygiene Considerations: Keep out of food and beverages
Section 9. Physical and Chemical Properties
Color: Gray to brown Odor: Spicy
Physical State: Granular Solid Odor Treshhold:
pH: Not applicable Freezing Point: Not applicable
Evaporation Rate: Not applicable Boiling Point: Not applicable
Flash Point: Not applicable Flammability(solid,gas): Not considered flammable.
Upper Flammability Limit: Not determined Lower Flammabilty Limit: Not determined
Vapor Pressure: Less than 1 Torr at 20°C Specific Gravity: Not determined. Bulk density greater than 0.75 g/mL
Vapor Density: Not determined Auto-ignition Temperature: Not determined
Volatile Organic Compound (VOC),%weight: Solubility (water): Insoluble
Less than 5%, all fragrance Percent Volatile: Less than 20% including water
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: None known
Incompatable Materials: Unsaturated organic compounds such as turpentine, vegetable oil, and hydrofluoric acid may generate heat when mixing with dry clay.
Hazardous Decomposition Products: None known
Possibility of Hazardous Reactions: Extremely improbable
Section 11. Toxicology Information
ACCUTE EFFECTS
Oral LD50: Not determined for mixture. Weighted average more than 6 grams per kilogram, acute.
Dermal LD50: Not considered toxic by skin contact. Weighted average more than 5 grams per kilogram, acute.
Inhalation: Not considered acutely toxic by inhalation. Weighted average more than 4 milligrams per Liter.
Eye Irritation: Direct contact with fine particles can irritate eyes
Skin Irritation: Prolonged or repeated contact can irritate skin
Sensitization: Sensitivity to residual silica may occur after long term exposure.
CHRONIC EFFECTS
Carcinogenicity: Mixture contains zeolite which is Class 3 (not classifiable to humans) by IARC. Residual Silica is a suspected carcinogen however the low levels in this product would not cause adverse effects with normal use.
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: None known
Persistence/Degradability: None known.
Bioaccumulation/Accumulation: Mineral carrier is persistent. Fragrance is biodegradable.
Mobility in Enviroment: None known
Section 13. Disposal Considerations
Disposal: Mineral carrier is not mobile.
Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Dispose according to Federal, State or Provincial, and Local regulations
CANADA TDG (ground)
Proper Shipping Description: Not a Hazardous Material
ICAO (air)
Proper Shipping Description: Not a Dangerous Good
IMDG (water)
Proper Shipping Description: Not a Dangerous Good
Section 15. Regulatory Information
Global Inventories  
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included
   
SARA 313 Information : Does not contain reportable concentrations of any SARA 313 Substances
 
California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
Not classifiable by IARC. Product mixture may contain negligible amounts of silica.
WHMIS: Canadian Workplace Hazardous Material Information System
D 2 B
Section 16. Other Information
Legends:  
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard
   
Prepared By: Technical Dept.
   
While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws.